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2-[(4-Bromophenyl)(4-fluorophenylamino)methyl]cyclohexanone

✍ Scribed by Yuan, Guang-Xin ;Sun, Jing-Bo ;Zhang, Li-Hua ;Lu, Gang

Book ID
104491527
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
973 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of the title compound, C 19 H 19 BrFNO, molecules are connected into dimers via intermolecular N-HÁ Á ÁO hydrogen bonding. The dihedral angle between the two benzene rings is 74.84 (1) . The cyclohexane ring has the usual chair conformation.

Related literature

For related literature, see: Shou et al. (2006). Experimental Crystal data C 19 H 19 BrFNO M r = 376.26 Monoclinic, P2 1 =n a = 12.6501 (14) A b = 8.2310 (9) A c = 17.0111 (18) A = 103.031 (2) V = 1725.6 (3) A ˚3 Z = 4 Mo K radiation = 2.40 mm À1 T = 295 (2) K 0.37 Â 0.31 Â 0.17 mm Data collection Bruker SMART CCD area-detector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1996) T min = 0.450, T max = 0.660 8450 measured reflections 3060 independent reflections 1669 reflections with I > 2(I) R int = 0.120 Refinement R[F 2 > 2(F 2 )] = 0.048 wR(F 2 ) = 0.113 S = 0.82 3060 reflections

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