The title compound, C~17~H~15~BrO~2~S, was prepared by the oxidation of 2-(4-bromophenyl)-5,7-dimethyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The 4-bromophenyl ring is rotated out of the benzofuran plane, with a dihedral angle of 19.3 (2)°. The O atom and the methyl group of th
2-(4-Bromophenyl)-5-methyl-3-methylsulfinyl-1-benzofuran
✍ Scribed by Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 1023 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, C 16 H 13 BrOS, was prepared by the Lewis acid-catalysed reaction of 4 0 -bromo-1,1 0 -biphenyl-4-ol withchloro--(methylsulfanyl)acetone. The crystal structure is stabilized by a C-HÁ Á Á interaction involving a CH group of the 4-bromophenyl ring and the furan ring.
The title compound, C 16 H 14 O 2 S, was prepared by oxidation of 2-methyl-3-methylsulfanyl-5-phenyl-1-benzofuran using 3chloroperbenzoic acid. Shortstacking distances are prevented by the steric influence of the methylsulfinyl group.
The title compound, C 10 H 9 ClO 2 S, was prepared by the oxidation of 5-chloro-2-methyl-3-methylsulfanyl-1-benzofuran using 3-chloroperbenzoic acid. The benzofuran ring system is almost planar. Noor -CH 2 -HÁ Á Á interactions were observed.
The title compound, C 16 H 14 O 2 S, was prepared by the oxidation of 3,5-dimethyl-2-phenyl-1-benzofuran using 3chloroperbenzoic acid. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The phenyl ring is rotated out of th