2-(4-Bromophenyl)-1-(methylsulfanyl)naphtho[2,1-b]furan
✍ Scribed by Choi, Hong Dae ;Seo, Pil Ja ;Son, Byeng Wha ;Lee, Uk
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 715 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 14 H 12 O 2 S, was prepared by the oxidation of 2-methyl-1-(methylsulfanyl)naphtho[2,1-b]furan using m-chloroperbenzoic acid. The crystal structure contains aromaticstacking, C-HÁ Á ÁO and C-HÁ Á Á interactions.
The title compound, C 19 H 13 BrOS, was prepared by the Lewis acid-catalysed reaction of 6-bromo-2-naphthol with 2-chloro-2-(methylsulfanyl)acetophenone. The naphthofuran ring system is nearly planar. The crystal structure is stabilized by a C-HÁ Á Á interaction.
The title compound, C~17~H~13~BrO~3~S, was prepared by alkaline hydrolysis of ethyl 2-[5-(4-bromophenyl)-3-methylsulfanyl-1-benzofuran-2-yl]acetate. There are two symmetry-independent molecules in the asymmetric unit. The 4-bromophenyl rings are rotated out of the benzofuran planes, with dihedral an