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2-(3-Methyl-1,2-buta­dienyl)-2-oxo-1,3,2-ox­aza­phospho­rinane

✍ Scribed by Angelov, Christo M. ;Mazzuca, Dean A. ;Heever, Johan P. van den ;McDonald, Robert ;McEwen, Alexander J. B. ;Mercer, John R.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
252 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The structure of the title compound, C 8 H 14 NO 2 P, the ®rst of a compound containing a 1,2-butadienyl group bound to the phosphorus of a 1,3,2-oxazaphosphorinane ring, is reported.

Experimental

Compound (2) was recrystallized from THF to give light-yellow crystals, with m.p. 383 K; 31 P NMR (CDCl 3 , versus ext. 85% H 3 PO 4 ) 15.5.

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