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[2 + 2] Photoaddition of 2-aminopropenenitriles to diarylethanediones. A product study

✍ Scribed by Dietrich Döpp; Michael-Alexander Fischer


Book ID
104589791
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
663 KB
Volume
114
Category
Article
ISSN
0165-0513

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Thiopyridonc ( I a) and 2-thiopyrimidone (1 bl undcrgo photoaddition to olefins 10 give ?-substituted hetcrocyclcs, probably via rhietanes formed by [ 2 i -21 addition across the C=S bond. A novel two-fold addition of isobutene is discussed.