Photoaddition of 2-thiopyridone and 2-thiopyrimidone to olefins
✍ Scribed by Sato, Eisuke ;Hasebe, Masato ;Nishio, Tamami ;Ikeda, Yoshiya ;Kanaoka, Yuichi
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 292 KB
- Volume
- 1988
- Category
- Article
- ISSN
- 0947-3440
No coin nor oath required. For personal study only.
✦ Synopsis
Thiopyridonc ( I a) and 2-thiopyrimidone (1 bl undcrgo photoaddition to olefins 10 give ?-substituted hetcrocyclcs, probably via rhietanes formed by [ 2 i -21 addition across the C=S bond.
A novel two-fold addition of isobutene is discussed.
📜 SIMILAR VOLUMES
## Abstract Substituted 1‐acetonaphthones 6b–d and 2‐morpholinoacrylonitrile (2a) undergo a photocycloaddition. The type of addition ([2 + 2] vs. [4 + 2]) is dependent on the location of additional substituents. Whereas compound 6c with a methoxy group at C‐2 gave only the [4 + 2]‐cycloadduct 11, t
## Abstract Photoirradiation of acetone solutions of 2,3‐diallyl‐6,7‐dihydro‐5__H__‐2a‐thia(2a‐S^IV^)‐2,3,4a, 7a‐tetraazacyclopent[__cd__]indene‐ 1,4(2__H__,3__H__)‐dithione (**1**) in the presence of excess thioacetic acid and thiobenzoic acid afforded addition products, 2,3‐bis(3‐acetylthiopropyl