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2-(2-Methyl-1,3-propanediol)-4,4,5,5-tetramethyl-3-oxylimidazoline 1-Oxide − An Antiferromagnetically Coupled Nitronyl Nitroxide

✍ Scribed by Robin Endtner; Christoph Loick; Eva Rentschler; Willi Sicking; Roland Boese; Reiner Sustmann


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
346 KB
Volume
2001
Category
Article
ISSN
1434-193X

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The reaction of 3-hydroperoxy-4,4,5,5-tetramethyl-3phenyl-1,2-dioxolane, 1, with a series of sulfides (2a ‫ס‬ thioanisole, 2b ‫ס‬ ethyl phenyl sulfide, 2c ‫ס‬ 2-chloroethyl phenyl sulfide, and 2d ‫ס‬ 2-chloroethyl methyl sulfide) at 34ЊC in various solvents yielded the corresponding sulfoxides and 3