## Abstract The disilane/disilylmethane rearrangement of an optically active disilanyl sulfide **9B** was used to prepare an optically active disilylalkene **10** whose absolute configuration was established by X‐ray analysis of the bromo derivative **13** (__P__2~1~, __a__ = 7.847 (3) Å, __b__ = 9
[2 + 2] cycloaddition of optically active ketenes. Synthesis of (−)-blastmycinone. Preliminary Communication
✍ Scribed by Georg Fráter; Urs Müller; Wulf Günther
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- German
- Weight
- 228 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0018-019X
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