In the molecule of the title compound, C~22~H~16~FN~3~O~3~, intramolecular C—H...F hydrogen bonding results in the formation of a six-membered ring. In the crystal structure, intermolecular C—H...O hydrogen bonds link the molecules into centrosymmetric dimers. The packing is further stabilized by π–
2-(1H-Benzotriazol-1-yl)-1-(4-fluorobenzoyl)ethyl nicotinate
✍ Scribed by Bi, Sai ;Luo, Hao ;Zeng, Wu-Lan ;Wan, Jun
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 980 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
There are two molecules in the asymmetric unit of the title compound, C 21 H 15 FN 4 O 3 . In the crystal structure, two intramolecular C-HÁ Á ÁO hydrogen bonds form two fivemembered rings. The molecules are linked into infinite chains along the b axis by intermolecular C-HÁ Á ÁO hydrogen bonds, and further linked by C-HÁ Á ÁN interactions along the a axis. The packing is further stabilized by C-HÁ Á Á interactions.
📜 SIMILAR VOLUMES
In the crystal structure of the title compound, C 22 H 15 ClFN 3 O 3 , the crystal packing is controlled by van der Waals forces. Weak intramolecular C-HÁ Á ÁO and C-HÁ Á ÁF hydrogen bonds link the molecules into chains extended along the c axis.The packing is further stabilized by van der Waals for
The molecules of the title compound, C 21 H 14 Cl 2 N 4 O 3 ÁH 2 O, are linked into dimers by C-HÁ Á ÁO hydrogen bonds and are linked into chains along the b axis by C-HÁ Á ÁO and O-HÁ Á ÁN hydrogen bonds involving the solvent water molecule. The packing is further stabilized byinteractions. 1 2 À z
In the title compound, C~21~H~15~ClN~4~O~3~, molecules are linked into dimers by C—H...O hydrogen bonds and are linked into chains along the __a__ axis by C—H...N intermolecular hydrogen bonds. The packing is further stabilized by C—H...π and π–π interactions.
In the title compound, C 24 H 21 N 3 O 3 , the relative orientation of the three rings is determined by the sp 3 -hybridization character of the chiral atom. The molecules are linked into ribbons along the b axis by intermolecular C-HÁ Á ÁO interactions.