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2-(1H-Benzotriazol-1-yl)-1-(2-fluorobenzoyl)ethyl benzoate

✍ Scribed by Bi, Sai ;Luo, Hao ;Zeng, Wu-Lan ;Wan, Jun

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
709 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the molecule of the title compound, C~22~H~16~FN~3~O~3~, intramolecular C—H...F hydrogen bonding results in the formation of a six-membered ring. In the crystal structure, intermolecular C—H...O hydrogen bonds link the molecules into centrosymmetric dimers. The packing is further stabilized by π–π interactions [centroid–centroid distance = 3.601 (2) Å].

📜 SIMILAR VOLUMES

2-(1H-Benzotriazol-1-yl)-1-(4-fluorobenz
2-(1H-Benzotriazol-1-yl)-1-(4-fluorobenzoyl)ethyl nicotinate
✍ Bi, Sai ;Luo, Hao ;Zeng, Wu-Lan ;Wan, Jun 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 980 KB

There are two molecules in the asymmetric unit of the title compound, C 21 H 15 FN 4 O 3 . In the crystal structure, two intramolecular C-HÁ Á ÁO hydrogen bonds form two fivemembered rings. The molecules are linked into infinite chains along the b axis by intermolecular C-HÁ Á ÁO hydrogen bonds, and

2-(1H-1,2,3-Benzotriazol-1-yl)-1-(2-fluo
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✍ Zeng, Wu-Lan ;Pang, Yan ;Zhang, Hua-Xiang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 559 KB

In the crystal structure of the title compound, C 22 H 15 ClFN 3 O 3 , the crystal packing is controlled by van der Waals forces. Weak intramolecular C-HÁ Á ÁO and C-HÁ Á ÁF hydrogen bonds link the molecules into chains extended along the c axis.The packing is further stabilized by van der Waals for

2-(1H-1,2,3-Benzotriazol-1-ylmeth­yl)-1-
2-(1H-1,2,3-Benzotriazol-1-ylmeth­yl)-1-benzoyl­ethyl 4-ethyl­benzoate
✍ Wan, Jun ;Peng, Zheng-Zhong ;Li, Xue-Mei ;Zhang, Shu-Sheng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 230 KB

In the title compound, C 24 H 21 N 3 O 3 , the relative orientation of the three rings is determined by the sp 3 -hybridization character of the chiral atom. The molecules are linked into ribbons along the b axis by intermolecular C-HÁ Á ÁO interactions.

2-(1H-1,2,3-Benzotriazol-1-yl)-1-benzoyl
2-(1H-1,2,3-Benzotriazol-1-yl)-1-benzoyl­ethyl 2-chloro­benzoate
✍ Wan, Jun ;Peng, Zheng-Zhong ;Li, Xue-Mei ;Zhang, Shu-Sheng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 201 KB

In the crystal structure of the title compound, C 22 H 16 ClN 3 O 3 , weak intermolecular C-HÁ Á ÁN hydrogen bonds link the molecules into chains extended along the c axis. The packing is further stabilized by weak C-HÁ Á ÁO interactions.