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2-{(1E)-1-[(4-Chlorophenyl)imino]ethyl}-4-methylphenol

✍ Scribed by Chang, Jian-Guo

Book ID
104491908
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
523 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, C~15~H~14~ClNO, displays a trans configuration with respect to the C=N double bond [C—C=N—C = 175.3 (2)°], with a twist by 58.67 (8)° of the two benzene rings about the cental C=N bond. The crystal structure is stabilized by intramolecular O—H...N and intermolecular C—H...O hydrogen bonds.

📜 SIMILAR VOLUMES

1-{(2-Chloro­phen­yl)[(4-methyl­phen­yl)
1-{(2-Chloro­phen­yl)[(4-methyl­phen­yl)imino]meth­yl}ferrocene
✍ Wang, Hong-Xing ;Zhou, Hui-Chao ;Wu, Hong-Fei 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 127 KB

The title compound, [Fe(C 5 H 5 )(C 19 H 15 ClN)], a new ketiminecontaining ferrocenyl derivative, has been synthesized and characterized structurally. Conjugation between the two benzene rings and the imine group is not observed. In addition, there are no significant intermolecular interactions.

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N-[1-(Benzyl­amino­carbon­yl)-2-(4-chloro­phen­yl)­ethyl]­benzamide
✍ Wen, Li-Rong ;Liu, Peng ;Li, Ming 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 472 KB

The title compound, C~23~H~19~ClN~2~O~2~, has been obtained by the reaction of (__Z__)-4-(4-chlorobenzylidene)-2-phenyloxazol-5(4__H__)-one and benzylamide. The molecules are connected by two N—H...O intermolecular hydrogen bonds to form helicoidal chains running parallel to the __c__ axis.

(E)-2-{1-[(4-Ethoxy­phenyl)­imino]eth­yl
(E)-2-{1-[(4-Ethoxy­phenyl)­imino]eth­yl}phenol
✍ Petek, Hande ;Albayrak, Çiğdem ;Ağar, Erb˙il ;Ískeleli, Nazan Ocak ;Şenel, Ismet 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 312 KB

The crystal structure of the title compound, C 16 H 17 NO 2 , contains two independent molecules in the asymmetric unit. Both molecules adopt the phenol-imine tautomeric form, with strong intramolecular O-HÁ Á ÁN hydrogen bonds. The crystal packing is stabilized by van der Waals interactions.

Ethyl 3-(4-chloro­phen­yl)-2-cyano­acryl
Ethyl 3-(4-chloro­phen­yl)-2-cyano­acrylate
✍ Zhang, Yue ;Liu, Jian-Wu 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 126 KB

The title compound, C 12 H 10 ClNO 2 , was synthesized by the reaction of ethyl cyanocaetate with 4-chlorobenzaldehyde in ethanol under microwave irradiation. In the crystal structure, weak intermolecular C-HÁ Á ÁO hydrogen bonds link the molecules into centrosymmetric dimers, which are held togethe

(1E,4E)-1,5-Bis(2-chlorophenyl)penta-1,4
(1E,4E)-1,5-Bis(2-chlorophenyl)penta-1,4-dien-3-one
✍ Nizam Mohideen, M. ;Thenmozhi, S. ;Subbiah Pandi, A. ;Murugan, Ramalingam ;Naray 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 304 KB

The title compound, C~17~H~12~Cl~2~O, crystallizes in a centrosymmetric space group. The dihedral angle between the two benzene rings is 24.7 (1)°. The crystal packing is characterized by non-classical C—H...O and C—H...Cl inter- and intramolecular hydrogen bonds.