We extend a detailed kinetic model for CO + O 2 on Pt{1 0 0} to describe pattern formation. The model includes: (i) a non-linear power law to describe the phase transition, (ii) trapping and untrapping processes explicitly considered, and (iii) experimentally determined coverage-dependent sticking p
〈1 0 0〉 Dislocations in nickel-base superalloys: Formation and role in creep deformation
✍ Scribed by T. Link; A. Epishin; M. Klaus; U. Brückner; A. Reznicek
- Book ID
- 104061062
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 824 KB
- Volume
- 405
- Category
- Article
- ISSN
- 0921-5093
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✦ Synopsis
a 1 0 0 Dislocations are observed in nickel-base superalloys after creep deformation at high temperatures and low stresses. They are formed in the ␥/␥ interfaces by a three step mechanism. First, primary dislocations with Burgers vector a/2 1 0 1 and 60 • character are left behind in the interfaces when dislocation loops glide through the ␥ channels. The 60 • dislocations move into edge orientation and react forming secondary dislocations a/2 1 1 0 . In the third step, new primary dislocations are knit into the already existing meshes of primary and secondary dislocations, which results in hexagonal misfit dislocation networks consisting of secondary dislocations a/2 1 1 0 and tertiary dislocations a 1 0 0 , both of edge type. This self-organisation process is explained by dislocation theory and crystallography.
Creep deformation accelerates when the a 1 0 0 interfacial dislocations enter the ␥ phase. During their climb towards the opposite interface, they attain a characteristic rectangular shape. This shape and the importance of the a 1 0 0 super dislocations for creep deformation are discussed.
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