Treatment of (1S,2S)-C 5 H 8 (PH 2 ) 2 (1) with OC(OCCl 3 ) 2 gave (Me)Et-(S)] 2 (5), P[2-OC 10 H 6 C 10 H 6 O-2Ј-(R)] (6), P(NC 4 H 8 O-(1S,2S)C 5 H 8 (PCl 2 ) 2 (2) as the first example of an optically cyclo) 2 (7), P(C 6 H 11 -cyclo) 2 (8)] by reactions with oxygen, active bis(phosphonous dichlor
(1S,2S)-(+)-1,2-Bis[(dicyclohexyl)phosphinomethyl]cyclopentane.2CS2 and (±)-1,2-Bis(dicyclohexylphosphinomethyl)cyclopentane
✍ Scribed by Tani, K. ;Onouchi, J. ;Yamagata, T. ;Kataoka, Y.
- Book ID
- 114512072
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 421 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
, was obtained by the direct reaction of NiCl 2 Á6H 2 O, K 2 imnt and (Bz2NH 2 py) + ÁBr À in water. The Ni II ion lies on an inversion centre and the asymmetric unit contains a (Bz2NH 2 py) + cation and one-half of the Ni(imnt) 2 2À anion. The Ni II ion adopts a square-planar coordination geometry.