Treatment of (1S,2S)-C 5 H 8 (PH 2 ) 2 (1) with OC(OCCl 3 ) 2 gave (Me)Et-(S)] 2 (5), P[2-OC 10 H 6 C 10 H 6 O-2Ј-(R)] (6), P(NC 4 H 8 O-(1S,2S)C 5 H 8 (PCl 2 ) 2 (2) as the first example of an optically cyclo) 2 (7), P(C 6 H 11 -cyclo) 2 (8)] by reactions with oxygen, active bis(phosphonous dichlor
ChemInform Abstract: Chiral Bisphosphanes. Part 7. (1S,2S)-Cyclopentane-1,2-diyl-bis(phosphonous dichloride), (1S,2S)-C5H8(PCl2)2 — A Versatile Optically Active Reagent.
✍ Scribed by L. DAHLENBURG; A. KAUNERT
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Four novel stereoisomers of 7-(1-phenylethyl)-2-oxa-7-azabicyclo[3.2.0]heptan-6-one were prepared under high pressure from [2 ] 2] cycloaddition of the pure enantiomers of 1-phenylethyl isocyanate and 2,3dihydrofuran. Their conformational preferences in solution and the absolute conÐgurations of the