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1H NMR studies on deuterium - hydrogen exchange at C-5 in uridines

✍ Scribed by Stephen R. Heller


Book ID
118850448
Publisher
Elsevier Science
Year
1968
Tongue
English
Weight
160 KB
Volume
32
Category
Article
ISSN
0006-291X

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Under strongly basic conditions (f-BuO-/f-BuOD at 185 "C), the 9,9-dirnethyltricycl0[5.2.1.0~~~]-and -[5.2.1.0'\*5]decan-8-ones and the homologous [5.3.1.0]undecanones undergo multi-site 'H/'H exchange. The total 2H uptake was monitored by mass spectrometry, while the individual sites of exchange we