1H NMR spectral properties and conformational preferences of some 1,2,9,10,17,18,25,26-octathia[2.2.2.2]-metacyclophanes
✍ Scribed by Giuseppe Ronsisvalle; Francesco Bottino; Sebastiano Pappalardo
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 309 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The stereochemistry in solution of three octathia[2.2.2.2]metacyclophanes has been investigated by means of ^1^H NMR spectroscopy. The results lead to the conclusion that the saddle or crown conformation is preferred for these compounds, depending on the substitution pattern of the constituent aromatic rings.
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