✦ LIBER ✦

1H NMR investigation of ring mobility of 1,5-benzodiazepine-2,4-diones

✍ Scribed by Giuseppe Chidichimo; Marcello Longeri; Giuseppina Menniti; Giovanni Romeo; Alida Ferlazzo

Publisher: John Wiley and Sons
Year: 1984
Tongue: English
Weight: 273 KB
Volume: 22
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.1270220111

No coin nor oath required. For personal study only.

✦ Synopsis

The ring mobility of some 1,5-benzodiazepine-2,4-diones and 1,4-benzodiazepin-2-one has been investigated by lhe temperature dependence of their 'H NMR spectra. The activation parameters have been obtained, and the influence of N-1 substitution on the ring mobiity is discussed, takiig into account previously reported data for similar compounds.

📜 SIMILAR VOLUMES

Carbon-13 NMR shift data of some 3H-1,4-

Carbon-13 NMR shift data of some 3H-1,4-benzodiazepine-2,5(1H, 4H)-diones

✍ Ghulam Mohiuddin; Padala Satyanarayana Reddy; Chengalvala Venkata Ratnam 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB

Carbon-13 chemical shifts of eight 3H-1,4-benzodiazepine-2,5( lH, 4H)-diones are reported. The carbonyl chemical shifts have diagnostic value for distinguishing these diones from the isomeric 1,3-benzodiazepine-2,5-dione structures.

Synthesis of 1,4-Benzodiazepine-2,5-dion

Synthesis of 1,4-Benzodiazepine-2,5-dione Derivatives.

✍ Tong-Ing Ho; Wen-Shiong Chen; Chi-Wei Hsu; Yeun-Min Tsai; Jim-Min Fang 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Synthesis of 1,4-Benzodiazepine-3,5-dion

Synthesis of 1,4-Benzodiazepine-3,5-diones.

✍ Per Wiklund; Mark Rogers-Evans; Jan Bergman 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Electron impact mass spectra of Some 3H-

Electron impact mass spectra of Some 3H-1,4-benzodiazepine-2,5-(1H,4H)-diones

✍ Ghulam Mohiuddin; Padala Satyanarayana Reddy; (late) Khalil Ahmed; Chengalvala V 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB

The synthesis of 7-chloro-5-pentadeuteri

The synthesis of 7-chloro-5-pentadeuteriophenyl-1-methyl-1h-1,5-benzodiazepine-2,4(3H, 5H)dione ([2H5]clobazam)

✍ Anthony G. Borel; Frank S. Abbott 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 French ⚖ 452 KB

## Abstract Pentadeuteriophenyl clobazam 5 was synthesized in essentially quantitative isotopic purity, and characterized by ^1^H‐NMR and mass spectroscopy. The title compound was found to be ≥98% pure by HPLC, and its retention time (t~R~ 6.17 min) was less than that of an authentic clobazam stand

Enantioselective Synthesis of Diversely

Enantioselective Synthesis of Diversely Substituted Quaternary 1,4-Benzodiazepin-2-ones and 1,4-Benzodiazepine-2,5-diones.

✍ Paul R. Carlier; Hongwu Zhao; Stephanie L. MacQuarrie-Hunter; Joseph C. DeGuzman 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 52 KB 👁 2 views