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1H ENDOR study, in single crystal, of a dissymmetrical [Fe4S4]+ state

✍ Scribed by L. Le Pape; B. Lamotte; J.-M. Mouesca; G. Rius

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
68 KB
Volume
59
Category
Article
ISSN
0162-0134

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Single-Crystal 57Fe Q-Band ENDOR Study o
Single-Crystal 57Fe Q-Band ENDOR Study of the 4 Iron–4 Sulfur Cluster in its Reduced [4Fe–4S]1+ State
✍ Fabrice Moriaud; Serge Gambarelli; Bernard Lamotte; Jean-Marie Mouesca πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 117 KB

57 Fe Q-band ENDOR has been used to study the [4Fe-4S] 1+ state created by Ξ³ irradiation of single crystals of the synthetic model compound [N(C 2 H 5 ) 4 ] 2 [Fe 4 S 4 (SCH 2 C 6 H 5 ) 4 ] enriched in 57 Fe. This compound is an excellent biomimetic model of the active sites of many 4 iron-4 sulfur