Single-Crystal 57Fe Q-Band ENDOR Study o
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Fabrice Moriaud; Serge Gambarelli; Bernard Lamotte; Jean-Marie Mouesca
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Article
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2001
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Elsevier Science
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English
β 117 KB
57 Fe Q-band ENDOR has been used to study the [4Fe-4S] 1+ state created by Ξ³ irradiation of single crystals of the synthetic model compound [N(C 2 H 5 ) 4 ] 2 [Fe 4 S 4 (SCH 2 C 6 H 5 ) 4 ] enriched in 57 Fe. This compound is an excellent biomimetic model of the active sites of many 4 iron-4 sulfur