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Detailed endor studies of the [Fe4S4]3+ paramagnetic state in single crystals of iron-sulfur cubane model compounds: I. 57Fe Hyperfine tensors

✍ Scribed by G. Rius; J.M. Mouesca; B. Lamotte


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
74 KB
Volume
36
Category
Article
ISSN
0162-0134

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Single-Crystal 57Fe Q-Band ENDOR Study o
✍ Fabrice Moriaud; Serge Gambarelli; Bernard Lamotte; Jean-Marie Mouesca πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 117 KB

57 Fe Q-band ENDOR has been used to study the [4Fe-4S] 1+ state created by Ξ³ irradiation of single crystals of the synthetic model compound [N(C 2 H 5 ) 4 ] 2 [Fe 4 S 4 (SCH 2 C 6 H 5 ) 4 ] enriched in 57 Fe. This compound is an excellent biomimetic model of the active sites of many 4 iron-4 sulfur