1H chemically induced dynamic nuclear polarization in the photodecomposition of uranyl carboxylates
✍ Scribed by Rykov, Stanislav V.; Khudyakov, Igor V.; Skakovsky, Eugeniy D.; Burrows, Hugh D.; Formosinho, Sebasti�o J.; da Gra�a M. Miguel, Maria
- Book ID
- 120212375
- Publisher
- Royal Society of Chemistry
- Year
- 1991
- Tongue
- English
- Weight
- 595 KB
- Volume
- 6
- Category
- Article
- ISSN
- 1472-779X
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📜 SIMILAR VOLUMES
## Abstract Thermolysis of di‐(4‐chlorobenzoyl)‐peroxide was carried out in the probe of an NMR. spectrometer. The dependence of product distribution and chemically induced dynamic nuclear polarization (CIDNP.) patterns on the concentrations of radical trapping agents gives evidence that the CIDNP.
CJDNP cffccts durmg bcnzoyl peroxide thermolysis have been measured duectly by a pulsed NMR spectrometer in Jaw magnetic fields (OS-120 Oe). It IF shown tilat the traditional technique of the sample "transfer" distorts the real magnetic ticld dcpendsncc of CJDNP.