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1H-Benzimidazole-1-carbohydrazonamide

✍ Scribed by Sokolov, Andrey V. ;Vologzhanina, Anna V. ;Purygin, Petr P.


Book ID
104487026
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
174 KB
Volume
62
Category
Article
ISSN
1600-5368

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The molecule of the title compound, C 18 H 18 N 4 , is disposed about a center of inversion. The dihedral angle between the five-and six-membered rings is 1.23 (6) , showing almost exact coplanarity. ## Experimental To a solution of benzimidazole (3 g, 25.42 mmol) in THF (30 ml) was added metalli

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In the molecule of the title compound, C 14 H 12 N 2 S, the benzimidazole ring system and the phenyl ring form a dihedral angle of 81.36 (7) . The crystal structure exhibits intermolecular C-HÁ Á ÁN and N-HÁ Á ÁN hydrogen bonds.

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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.041 wR factor = 0.105 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.