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1H and31P NMR study of Rh(I)trimethylphosphine complexes and their adducts with molecular oxygen

✍ Scribed by I. P. Kovalev; Yu. A. Strelenko; A. V. Ignatenko; M. G. Vinogradov; G. I. Nikishin

Book ID
112445904
Publisher
Springer
Year
1989
Tongue
English
Weight
295 KB
Volume
38
Category
Article
ISSN
1573-9171

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Liquid-phase stereochemistry of cationic
Liquid-phase stereochemistry of cationic [Rhbisphosphinediene]+ and neutral [RhbisphosphinedieneCl] complexes. 1H, 31P and 13C NMR and molecular mechanics study
✍ Gábor Szalontai; Péter Sándor; József Bakos 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 750 KB

## Abstract The liquid‐state stereochemistry of cationic [Rh(I)dienebisphosphine]^+^ and neutral [Rh(I)dienebisphosphineCl] complexes is reported on the basis of their ^1^H, ^13^C and ^31^P NMR spectra. In solution the 400‐MHz ^1^H spectra indicate __C__~2~ symmetry for the cationic species an