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Structure of Halogenophosphorincopper(I) Complexes in Solid State and Solution: Study with X-ray Crystallography and CP/MAS-31P{1H}-NMR Spectroscopy

✍ Scribed by Michito Shiotsuka; Takahiro Tanamachi; Tsuyoshi Urakawa; Megumu Munakata; Yoshihisa Matsuda


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
250 KB
Volume
2
Category
Article
ISSN
1472-7862

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A simple molecule with a complex crystal
✍ Klaus Eichele; Christiane Nachtigal; Susanne Jung; Hermann A. Mayer; Ekkehard Li 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 174 KB

## Abstract A comprehensive ^31^P solid‐state NMR study of Ru(η^1^‐Ph~2~PCH~2~CH~2~OCH~3~)~2~(η^2^‐en)Cl~2~ (en = ethylenediamine) (1), by 1D (contact time variation, inversion–recovery, SPARTAN) and 2D techniques (homonuclear __J__‐resolved, SECSY) indicated that the crystal structure of 1 should