€I and =C NMR spectral data for 21 N-rnethyltetrahydroquinoxalines annelated with furan, p p l e , imidazole or thiazole rings are reported. Unambiguous assignments of the ring junction =C resonances were made on the basis of selective decoupling experiments and with the aid of one-bond and long-ran
1H and 13C NMR spectra of tetrahydroquinoxalines condensed with six-membered heterocycles
✍ Scribed by V. N. Charushin; N. N. Sorokin; A. I. Chernyshev; V. G. Baklykov; M. G. Ponizovsky; O. N. Chupakhin
- Publisher
- John Wiley and Sons
- Year
- 1986
- Tongue
- English
- Weight
- 737 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0749-1581
No coin nor oath required. For personal study only.
✦ Synopsis
The 'H and uC NMR spectra of tetrahydroquinoxalines condensed with pyridazme, pyrazine, oxazine, oxadiazine, thiadiazine or triazine rings have been measured in DMSO-d, solution. The effects of six-membered heterocycles on 'H and uC chemical shifts and the values of one-bond 'J(CH) and vicinal 3J(HH) coupling constants for the ring junction fragment are considered. The differences between the 'H and =C spectral parameters of tetrahydroquinoxalines aunelated with fiveor six-membered heterocycles with the same set of heteroatoms attached to the ring junction carbons are also discussed.
KEY WORDS 'H NMR 13C NMR condensed tetrahydroquinoxalines.
📜 SIMILAR VOLUMES
0 'H-and 'W-NMR data and spectral assignments are reported for fenobam using noise modulated gated, single frequency off resonance, and single frequency selective proton decoupling techniques. Keyphrases 0 Fenobam-'H-and 13C-NMR spectroscopic analysis 0 'H-and 'T-NMR spectroscopy-analysis of fenoba
Proton and carbon-13 spectra of benzyl compounds of the general formula (C,H,CH,),X with a large variety of X substituents have been measured. While a linear relationship between the CH, chemical shift and the substituent electronegativity was found both for lH and lac, large deviations from lineari
## Abstract The ^1^H and ^13^C NMR spectra of 7,7′,8,8′‐tetradehydro‐4,5:4′,5′‐diepoxy‐17,17′‐dimethyl‐[2,2′‐bimorphinan]‐3,3′,6,6′‐tetrol; [2,2′‐bimorphine] (pseudomorphine) and 7,7′,8,8′‐tetradehydro‐4,5:4′,5′‐diepoxy‐17,17′‐dimethyl‐[2,2′‐bimorphinan]‐3,3′‐dimethoxy‐6,6′‐diol; 2,2′‐bimorphine (d
The 'H NMR and 13C NMR spectra of neopentyl and benzyl substituted disulfides, thiosulfinates, thiosulfonates, thiols, sulfides, sulfinic acids and sulfonic acids are reported. The deshielding electron withdrawing effects of -SO, -SO,, -SOz-, -SO,H, -SO,-, S 0 , H and S03CH3 on or-ðylene and benz
The 'H NMR spectrum of pentafulvalene has been analysed. Proton-proton coupling constants and I3C chemical shifts are compared with those of sterically similar pentafulvenes. Pentafulvalene can be regarded as a pentafulvene with a highly localized n-system.