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1H and 13C NMR spectra of pseudomorphine and dimethylpseudomorphine

✍ Scribed by D. W. Graden; G. W. Caldwell; F. J. Villani; C. A. Maryanoff; A. Grant


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
355 KB
Volume
28
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ^1^H and ^13^C NMR spectra of 7,7′,8,8′‐tetradehydro‐4,5:4′,5′‐diepoxy‐17,17′‐dimethyl‐[2,2′‐bimorphinan]‐3,3′,6,6′‐tetrol; [2,2′‐bimorphine] (pseudomorphine) and 7,7′,8,8′‐tetradehydro‐4,5:4′,5′‐diepoxy‐17,17′‐dimethyl‐[2,2′‐bimorphinan]‐3,3′‐dimethoxy‐6,6′‐diol; 2,2′‐bimorphine (dimethylpseudomorphine) were measured and assigned using DEPT, COSY, HETCOR, NOESY, NOE difference techniques and selective proton decoupled carbon NMR experiments.


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