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1H and 13C NMR assignments of conformationally defined 6- s-cis-retinoids

✍ Scribed by D. D. Muccio; Y. C. Lee; M. Alam; W. J. Brouillette

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 73 KB
Volume: 37
Category: Article
ISSN: 0749-1581
DOI: 10.1002/(sici)1097-458x(199901)37:1<82::aid-mrc381>3.0.co;2-m

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✦ Synopsis

Three examples of a new class of retinoic acid analogs (retinoids) were synthesized. These retinoids contain a dimethylene bridge to maintain a 6-s-cis conformation of the terminal double bonds, which is preferred in the major conformation of the natural compound. The 1H and 13C NMR spectra were assigned for 22 new compounds, including retinoid E/Z isomers (all-E, 13Z, 9Z) and selected intermediates. The assignments were based upon long-range 1HÈ13C heteronuclear 2D experiments.

1999 John Wiley & Sons, ( Ltd.

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