1H-1H correlations across N–H•••N hydrogen bonds in nucleic acids
✍ Scribed by Ananya Majumdar; Yuying Gosser; Dinshaw J. Patel
- Book ID
- 110321214
- Publisher
- Springer Netherlands
- Year
- 2001
- Tongue
- English
- Weight
- 354 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0925-2738
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The results of systematic ab initio calculations of 15 N and 1 H chemical shielding tensors in the GC base pair as a function of hydrogen bond length are presented for the first time. The hydrogen bond length characterized by the distance r N. . .N between purine N1 and pyrimidine N3 was varied betw
Transverse 1 H cross relaxation was observed in Carr-Purcell-Meiboom-Gill (CPMG) experiments by recording 15 N-1 H correlated spectra of amides in HIV protease that was perdeuterated at nonexchangeable sites. Perdeuteration suppresses 1 H-1 H J coupling and improves spectral resolution and sensitivi