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1H, 13C NMR, X-ray and conformational studies of new 1-alkyl-3-benzoyl-pyrazole and 1-alkyl-3-benzoyl-pyrazoline derivatives

✍ Scribed by Luisa C. López-Cara; M. Dora Carrión; M. Encarnación Camacho; Miguel A. Gallo; Antonio Espinosa; Duane Choquesillo-Lazarte; Josefa M. Gonzalez-Pérez; Antonio Entrena Guadix

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
240 KB
Volume
46
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^1^H and ^13^C NMR resonances of 22 1‐alkyl‐pyrazole and 25 1‐alkyl‐pyrazoline derivatives were assigned completely using the concerted application of one‐ and two‐dimensional experiments (DEPT, gs‐HMQC and gs‐HMBC). Nuclear Overhauser enhancement (NOE) effects, conformational analysis and X‐ray crystallography confirm the preferred conformation of those compounds. Copyright © 2008 John Wiley & Sons, Ltd.

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