The 'H and 13C N M R spectra of a series of benzoxazine, benzothiazine and quinazoline nitrate esters were measured and assigned on the basis of substituent chemical shifts and 13C1/H shift correlated experiments.
1H and 13C NMR study of new organic nitrate esters. I. (2H)-1,3-benzoxazin-4-(3H)-one derivatives
✍ Scribed by Giorgio Bertolini; Sonia Conti; Francesco Ferrario; Alberto Sala
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 196 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^1^H and ^13^C NMR of a series of 3‐nitrooxyalkyl‐2__H__‐1,3‐benzoxazin‐4‐(3__H__)‐ones were measured and assigned on the basis of substituent chemical shifts, DEPT experiments and ^13^C/^1^H shift correlated spectra.
📜 SIMILAR VOLUMES
The ' H and "C NMR of a series of benzoic acid-substituted nitrate esters were measured and assigned on the basis of substituent chemical shifts, COSY experiments and 13C,' H shift correlated spectra KEYWORDS 'H NMR; "C NMR; benzoic acid derivatives; organic nitrate esters
## Abstract A ^1^H and ^13^C NMR conformational study of four __cis__‐fused __N__‐substituted hexahydrocyclopent[__e__][1,3]oxazin‐4‐ones and four __cis__‐fused hexahydro‐2__H__‐1,3‐benzoxazin‐4‐ones at various temperatures revealed several dynamic conformational processes to be in effect. These in
## Abstract Substituted 2‐(benzylamino)‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐ones are unstable under alkaline and acidic conditions, undergoing opening of the benzoxazinone ring. 2‐Bromo‐2__H__‐1,4‐benzoxazin‐3(4__H__)‐ones show similar degradation under alkaline conditions, while replacement of Br at C