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17O Nuclear magnetic resonance and relaxation in some chlorine oxyfluorides

✍ Scribed by J. Virlet; G. Tantot


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
299 KB
Volume
44
Category
Article
ISSN
0009-2614

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✦ Synopsis


Natural abundance "0 NMR was studied in ClOaF, CIO,, CIOT3. ClOzr' and C102AsF6 as pure liquids or in solution. Chemiwl shifts are reported for all these compounds. In C103I'. a line shape analysis and a longitudmal relaxation mcxurement gives the indirect coupling constant J(Cl-"0) = 108 f 5 Hz and the quadrupolar interaction of "0, e*qQ/lz = 14 f 1.5 MIIZ.


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