𝔖 Bobbio Scriptorium
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172 Stereochemistry of glycosides as related to biological activity

✍ Scribed by C. Tamm

Book ID
115767756
Publisher
Elsevier Science
Year
1961
Tongue
English
Weight
117 KB
Volume
8
Category
Article
ISSN
0006-2952

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## Abstract The diastereomeric ceramides, (2__S__,3__S__,4__R__)‐, (2__S__,3__S__,4__S__)‐, (2__S__,3__R__,4__S__)‐, and (2__S__,3__R__,4__R__)‐2‐[(2__R__)‐2‐hydroxytetracosanoylamino]‐1,3,4‐hexadecanetriols 5–8 and the corresponding ceramide lactosides 1–4 have been synthesized. Compound 1 is almo

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Tlic first asymmetric synthesis of a phytosphingosine, (ZS,38,4R)-2-amino-1.3.4-hexadecanetriol (Z), was accomplishd by kinetic resolution and asymmetric cpoxidation. The absolute stereochcmislry of the phytosphingosine from starfishes (Amithasier plniici iind Astcrinrr prciin~jkrrr) was cstnblishcd