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1,6-epithio- and 1,6-episeleno-β-d-glucopyranose: Useful adjuncts in the synthesis of 6-deoxy-β-d-glucopyranosides

✍ Scribed by Robert V Stick; D Matthew; G Tilbrook; Spencer J Williams

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
144 KB
Volume
38
Category
Article
ISSN
0040-4039

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✦ Synopsis

The treatment of derivatives of 1,6-epithio-and 1,6-episeleno-/3-D-glucopyranose with various carbohydrate alcohols in the presence of N-iodosuccinimide/triflic acid gives rise to disulfides and diselenides, respectively, which may be transformed to the desired 6-deoxy-fl-D-glucopyranosides.

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