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15N nuclear magnetic resonance spectroscopy. Natural-abundance 15N spectra of aliphatic oximes

✍ Scribed by Robert E. Botto; Philip W. Westerman; John D. Roberts

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
560 KB
Volume
11
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^15^N chemical shifts of the Z and E isomers of twenty‐two ketoximes and fourteen aldoximes have been determined at the natural‐abundance level of ^15^N, using Fourier transform methods. The influences of π delocalization, methyl substituents and solute concentration on the oxime nitrogen shielding have been determined. The ^15^N shifts for oximes of several cycloalkanones have been measured and the influence of ring size on the chemical shifts is discussed.

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