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15N NMR spectroscopic determination of the structure of trimethylsilyl derivatives of acylated and carboxylated hydrazines. Communication 1. The structures of 1,2-diacetyl- and 1,2-dicarbomethoxyhydrazines

✍ Scribed by B. N. Khasapov; A. V. Kalinin; A. Ya. Shteinshneider; A. A. Blyumenfel'd; S. L. Ioffe; V. A. Tartakovskii


Book ID
112442764
Publisher
Springer
Year
1984
Tongue
English
Weight
510 KB
Volume
33
Category
Article
ISSN
1573-9171

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Diphenyl-1,2-bis(trimethylsilyl)ethene (5) undergoes a determined by NMR spectroscopy ( 1 H, 13 C, 6 Li, 7 Li NMR and 6 Li, 1 H-HOESY). It is shown that the phenyl rings have a high smooth reductive metallation with metallic lithium to yield the corresponding dilithioethane derivative (Li 2 β€’5). The