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NMR Investigation on the Solution Structure and Dynamic Behaviour of 1,2-Diphenyl-1,2-bis(trimethylsilyl)ethanediyldilithium

✍ Scribed by Alois Fürstner; Günter Seidel; Hans-Egbert Mons; Richard Mynott

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
143 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

Diphenyl-1,2-bis(trimethylsilyl)ethene (5) undergoes a determined by NMR spectroscopy ( 1 H, 13 C, 6 Li, 7 Li NMR and 6 Li, 1 H-HOESY). It is shown that the phenyl rings have a high smooth reductive metallation with metallic lithium to yield the corresponding dilithioethane derivative (Li 2 •5). The quinoid character and that the lithium cations are relatively mobile. structure of this new compound in [D 8 ]THF solution was

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