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15N NMR spectroscopic determination of the Si ← N bond length in 1-halosilatranes

✍ Scribed by V. A. Pestunovich; B. Z. Shternberg; L. P. Petukhov; V. I. Rakhlin; V. P. Baryshok; R. G. Mirskov; M. G. Voronkov


Book ID
112442614
Publisher
Springer
Year
1985
Tongue
English
Weight
69 KB
Volume
34
Category
Article
ISSN
1573-9171

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A method based on rotational-echo double-resonance (REDOR) NMR is proposed to measure 1 H-15 N bond lengths under magic-angle-spinning. Protons are selectively polarized and evolve under the frequency-switched Lee-Goldburg (FSLG) homonuclear decoupling, while two 15 N p pulses are applied to restore