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15N NMR of stable nitroxides

✍ Scribed by I.A. Grigor'ev; L.B. Volodarsky; A.Z. Gogolev; R.Z. Sagdeev


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
370 KB
Volume
122
Category
Article
ISSN
0009-2614

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✦ Synopsis


15N NMR spccua of ni1ro.xide.s in solutions have been smdied for Ihe lirst rime. The hli constams for II& nilrogen atoms 01 nirrone and imine groups (a?) and also Tar nitrogen atoms 01 luncrional groups in posiCon 4 of imidazoline niwoxides have been drlermined. The influence 01 structural parameters on isotropic hli consmnls has been analyzed.


πŸ“œ SIMILAR VOLUMES


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13C NMR spectra of the 15 stable imidazoline r&oxides have been studied. It has been shown that introduction of the N-oside oxygen atom to the 3 position is most favourable for penetration of the spin density to the C=N group of the imidazoline cycle. and for its effective migration about the conjug

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## Abstract Line intensities in ^15^N NMR spectra are strongly influenced by spin‐lattice and spin–spin relaxation times, relaxation mechanisms and experimental conditions. Special care has to be taken in using ^15^N spectra for quantitative purposes. Quantitative aspects are discussed for the ^15^