13C NMR spectra of the 15 stable imidazoline r&oxides have been studied. It has been shown that introduction of the N-oside oxygen atom to the 3 position is most favourable for penetration of the spin density to the C=N group of the imidazoline cycle. and for its effective migration about the conjug
15N NMR of stable nitroxides
β Scribed by I.A. Grigor'ev; L.B. Volodarsky; A.Z. Gogolev; R.Z. Sagdeev
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 370 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
15N NMR spccua of ni1ro.xide.s in solutions have been smdied for Ihe lirst rime. The hli constams for II& nilrogen atoms 01 nirrone and imine groups (a?) and also Tar nitrogen atoms 01 luncrional groups in posiCon 4 of imidazoline niwoxides have been drlermined. The influence 01 structural parameters on isotropic hli consmnls has been analyzed.
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