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[14C]Senecionine and [14C]isosenecionine from the pyrrolizidine alkaloid retrorsine

✍ Scribed by A. Robin Mattocks

Publisher: John Wiley and Sons
Year: 1983
Tongue: French
Weight: 419 KB
Volume: 20
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.2580200215

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✦ Synopsis

Abstract

Retrorsine (1) has been oxidized to a mixture of two epimeric cyclic keto esters (2) which, [^14^C]methylmagnesium iodide gave [18‐^14^C]senecionine (3a) and [18‐^14^C] isosenecionine (3d).

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