1,4-trans-Polymerization of Dienes: 1. Synthesis of Polybutadiene in the Presence of Mixed Systems Based on VOCl3and Titanium Compounds
✍ Scribed by I. R. Mullagaliev; E. Yu. Kharitonova; Yu. B. Monakov
- Book ID
- 106449570
- Publisher
- Springer
- Year
- 2005
- Tongue
- English
- Weight
- 92 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0023-1584
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## Abstract 1,3‐Butadiene, 4‐methyl‐1,3‐pentadiene and styrene were polymerized with dicyclopentadienyltitanium dichloride/methylaluminoxane (Cp~2~TiCl~2~/MAO) and dicyclopentadienyltitanium chloride/MAO (Cp~2~TiCl/MAO). These systems are less active than cyclopentadienyltitanium trichloride/MAO (C
## Abstract **Summary:** Homopolymerization of 4‐methyl‐1,3‐pentadiene (MP) and copolymerization of 4‐methyl‐1,3‐pentadiene with alkenes (ethylene, 1‐pentene, 4‐methyl‐1‐pentene) were performed to investigate the effect of the so‐called backbiting coordination on the chemoselectivity of 1,3‐diene p