𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1,4-Silyl migration from oxygen to carbon in silyl allyl ethers: Kinetic and thermodynamic factors

✍ Scribed by Terence N Mitchell; Marc Schütze


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
481 KB
Volume
55
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Reversible 1,4 migration of a silyl grou
✍ J. Mora; A. Costa 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 203 KB

## Anions generated from trialkylsilyl ethers of methyl ketoximes (1) undergo anionic rearrangement with 1,4 migration of the silyl group. After protonation, the resulting a-trialkylsilyl ketoximes (2), suffer thermal rearrangement with 1,4 migration of the silyl group from carbon to oxygen.