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1,4-Diphospha-1,3-butadienes

✍ Scribed by Prof. Dr. Rolf Appel; Johannes Hünerbein; Nikolaos Siabalis

Publisher: John Wiley and Sons
Year: 1987
Tongue: English
Weight: 230 KB
Volume: 26
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198707791

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1,4-Diphospha-1,3-butadiene

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Reactions of a sterically protected 2,3-

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✍ Shigekazu Ito; Kozo Toyota; Masaaki Yoshifuji 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

The reactions of 2,3-dichloro-1,4-diphospha-1,3-butadiene, which is sterically protected with the 2,4,6-tri-t-butylphenyl group, with some nucleophiles, including alkyllithium reagents and lithium aluminum hydrides, afforded 1,2-diphosphinoacetylenes or 3-phosphino-1-phosphaallenes.