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1,4-Diphospha-1,3-butadiene

✍ Scribed by Prof. Dr. Rolf Appel; Johannes Hünerbein; Nikolaos Siabalis


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
238 KB
Volume
99
Category
Article
ISSN
0044-8249

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The reactions of 2,3-dichloro-1,4-diphospha-1,3-butadiene, which is sterically protected with the 2,4,6-tri-t-butylphenyl group, with some nucleophiles, including alkyllithium reagents and lithium aluminum hydrides, afforded 1,2-diphosphinoacetylenes or 3-phosphino-1-phosphaallenes.