๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

1,4-Dimethyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione: optical resolution, absolute configuration and circular dichroism

โœ Scribed by Igor V. Vystorop; Andrei N. Utienyshev; Victor M. Anisimov; Remir G. Kostyanovsky


Book ID
111730244
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
192 KB
Volume
9
Category
Article
ISSN
0959-9436

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


ChemInform Abstract: Optically Active 2,
โœ Remir G. Kostyanovsky; Pavel E. Dormov; Peteris Trapencieris; Boriss Strumfs; Gu ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB ๐Ÿ‘ 1 views

The racemic title bicycle (V) undergoes spontaneous resolution on crystallization from chloroform or acetone. The absolute configuration of the obtained enantiopure product (16-44% e.e.) is determined by comparison with (S)-(V) derived from (S)-Ser-OMe (I). Mutarotation due to partial conversion of