𝔖 Bobbio Scriptorium
✦   LIBER   ✦

1,4-Dihydro-6-methyl-5-(N-methyl­carbamo­yl)-4-(4-nitro­phen­yl)pyrimidine-2(3H)-thione monohydrate

✍ Scribed by Sridhar, Balasubramanian ;Ravikumar, Krishnan

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
127 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 13 H 14 N 4 O 3 SÁH 2 O, is an isomer of 1,4dihydro-6-methyl-5-(N-methylcarbamoyl)-4-(2-nitrophenyl)pyrimidine-2(3H)-thione. The nitro group is coplanar with the benzene ring to which it is attached. Intermolecular hydrogen bonds stabilize the crystal structure.

📜 SIMILAR VOLUMES

4-(2,4-Dichloro­phen­yl)-5-(N,N-diethyl­
4-(2,4-Dichloro­phen­yl)-5-(N,N-diethyl­carbamo­yl)-6-methyl-3,4-dihydro­pyrimidine-2(1H)-thione
✍ Sridhar, B. ;Ravikumar, K. ;Sadanandam, Y. S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 140 KB

The asymmetric unit of the title compound, C 16 H 19 Cl 2 N 3 OS, contains two crystallographically independent molecules, which have almost identical conformations. The dihydropyrimidine ring adopts a boat conformation in both molecules. N-HÁ Á ÁO and N-HÁ Á ÁS hydrogen bonds stabilize the crystal

4-(4-Chloro­phen­yl)-5-(4-methyl­phen­yl
4-(4-Chloro­phen­yl)-5-(4-methyl­phen­yl)-3-(2-pyrid­yl)-4H-1,2,4-triazole
✍ Zhang, Shu-Ping ;Liu, Zhao-Di ;Shao, Si-Chang 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 136 KB

In the title compound, C~20~H~15~ClN~4~, the two benzene rings form dihedral angles of 30.95 (9) and 70.69 (6)° with the triazole ring, and the dihedral angle between the triazole and the pyridine rings is 43.38 (8)°. Intermolecular C—H...N hydrogen bonds are observed in the crystal structure.