1,4-dicyanobutene-bridged binuclear rhodium(I) complexes and their catalytic activities
β Scribed by Hwa-Kun Park; In Bum Kim; Chong Shik Chin
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 429 KB
- Volume
- 326
- Category
- Article
- ISSN
- 0022-328X
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π SIMILAR VOLUMES
Reactions of dimeric complex [Rh(CO) 2 Cl] 2 (1) with pyridine ester ligands methyl picolinate (a), methyl nicotinate (b), methyl isonicotinate (c), ethyl picolinate (d), ethyl nicotinate (e) and ethyl isonicotinate (f) in the 1:2 molar ratio afford the complexes of the type [Rh(CO) 2 ClL] (1a-f). T
The water-soluble phosphine ligands, 1,3,5triaza-7-phosphatricyclo[3.3.1.1 3,7 ]decane (tpa) and 1-alkyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.1 3,7 ]decane iodides (Rtpa I Γ ), with alkyl=methyl(mtpa I Γ ), ethyl (etpa I Γ ) and npropyl, (ptpa I Γ ), and mtpa Cl Γ react with [Rh 2 Cl 2 (CO) 4
## Abstract The title complex [(H~2~O)~2~(IMI)~3~Ni(TCB)Ni(IMI)~3~β(H~2~O)~2~] H~2~O (TCB = 1,2,4,5βbenzenetetracarboxylato teβtravalent anion; IMI = imidazole) has been prepared by the reaction of Ni(IMI)~3~(Ac)~2~ and TCB in aqueous solution. The crystal structure has been determined by singleβcr
## Abstract For Abstract see ChemInform Abstract in Full Text.