1,4-Bis(4-dimethylaminobenzyl)-2,3-diaza-1,3-butadiene
✍ Scribed by Wang, Qing-Hua ;Guo, Guo-Cong ;Wang, Ming-Sheng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 172 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title Schiff base compound, C 18 H 22 N 4 , is derived from the condensation reaction of hydrazine and 4-(dimethylamino)benzaldehyde. There is a crystallographic centre of symmetry at the mid-point of the N-N bond.
📜 SIMILAR VOLUMES
In the title compound, C 18 H 20 N 4 O 2 , the triazole ring is twisted with respect to the two benzene rings with dihedral angles of 71.5 (3) and 67.3 (3) . N-HÁ Á ÁN hydrogen bonding occurs between neighboring molecules.
In the crystal structure of the title compound, C 18 H 14 Cl 2 N 2 O 2 , there are weak intermolecular C-HÁ Á ÁO hydrogen-bond interactions. In the title molecule, the plane of the pyrimidine ring makes angles of 71.6 (1) and 71.72 (9) with the planes of the two benzene rings.
The title compound, C 20 H 16 N 6 , consists of electron-delocalized trans-planar molecules possessing a crystallographically imposed centre of symmetry. In the crystal packing, the molecules are stacked along the c axis by van der Waals forces.