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13C1H dipolar recoupling dynamics in 13C multiple-pulse solid-state NMR

✍ Scribed by Yoshitaka Ishii; Jun Ashida; Takehiko Terao

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
449 KB
Volume
246
Category
Article
ISSN
0009-2614

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✦ Synopsis

The recoupling of ~3C-IH dipolar interactions by applying ~3C pulses under a ~H decoupling rf field is discussed. It is theoretically and experimentally shown that ]3C spectral line-broadening due to such recoupling in a ]3C "n-pulse train can be minimized by setting the rf field intensity for ~H decoupling to around three times that for I3C "i'¢ pulses, or stronger.

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