## Abstract Evaluation by empirically derived equations for the substituent effect (α, β, γ, δ) on the ^13^C NMR chemical shifts for C‐3, C‐4, C‐5 and halomethyl‐substituent carbon (C‐6) in 5‐halomethyl‐5‐hydroxy‐4,5‐dihydroisoxazoles (where C‐3 substituent=H), alkyl or phenyl, C‐4 substituent=H, a
13C NMR substituent chemical shifts in hydroxy-p-benzoquinones
✍ Scribed by Eleuterio Burgueño-Tapia; Pedro Joseph-Nathan
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 55 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0749-1581
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📜 SIMILAR VOLUMES
NMR chemical shifts for some a-heterosubstituted acetones were recorded. The carbonyl carbon shieldings are discussed in the light of the substituent electronic effects and were also empirically estimated by Tanaka et d ? s equation. An approximate linear relationship was observed between the I3C an
## Abstract ^13^C NMR Substituent chemical shift (SCS) increments have been determined for the carbonyl carbon of a variety of substituted benzaldehydes and acetophenones. The ^13^C NMR chemical shift of the carbonyl carbon can be predicted for many di‐ and trisubstituted benzaldehydes and acetophe
## Abstract The effects of an hydroxy substituent on ^13^C^13^C coupling constants and ^13^C chemical shifts have been measured in 1‐hydroxynaphthalene‐2‐^13^C and 1‐hydroxypyrene‐1‐^13^C. The changes observed in the ^13^C^13^C couplings show the effect of a substituent attached directly to the l
## Abstract The analysis of the ^13^C NMR chemical shifts of 16 substituted 2‐phenylthiazolidines shows that the 1,3‐thiazolid‐2‐yl group exerts a deshielding effect at the __ipso__ carbon (C‐1′) and shielding effects at the __ortho__ and __para__ positions of the benzene ring (C‐2′ and C‐4′), and
## Abstract ^13^C chemical shifts and ^31^P,^13^C coupling constants are reported for nine 1‐hydroxyalkylphosphonic and two additional phosphonic acids. The α‐substituent‐induced chemical shifts (α‐SCS) of the phosphonate group were calculated and their non‐additivity was observed. Good linear corr