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13C NMR study of (propargyl)dicobalt hexacarbonyl cations: A structurally unique class of metal-stabilized carbenium ions

โœ Scribed by S. Padmanabhan; K.M. Nicholas

Book ID
103224730
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
37 KB
Volume
268
Category
Article
ISSN
0022-328X

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Transition metal-stabilized carbenium io
Transition metal-stabilized carbenium ions as synthetic intermediates. II. Alkylation of ฮฒ-dicarbonyl compounds with (propargyl)dicobalt hexacarbonyl cations
โœ H.Daniel Hodes; Kenneth M. Nicholas ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 193 KB

As part of a program to investigate the potential synthetic utility of transition metal-stabilized carbenium ions , we have been interested in the +1 chemistry of the cationic propargyl complexes (RCICCR2)y2(C0)6. Since the activating -Co2(CO)6 moiety is efficiently introduced and removed, 3 these c