The complete assignments of the 13C NMR resonances of N-(alkanoyl)-and N-(3-oxoalkanoyl)-S-homoserine lactone are reported. These assignments were made by comparison with values for N-butanoyl-S-homoserine lactone, a model compound whose structure was comprehensively established by a combination of
13C NMR study of N-acyl- and N-sulphonyl-isatins and their ring-opened derivatives
✍ Scribed by E. Charles Angell; David St C. Black; Naresh Kumar
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 242 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The complete assignments of the ^13^C NMR resonances of 1‐acetyl‐, 1‐benzoyl‐, 1‐benzenesulphonyl‐, 1‐methanesulphonyl‐ and 1‐(2‐nitrobenzenesulphonyl)‐isatins and their ring‐opened glyoxylic derivatives are reported. The ^13^C assignments of acylisatins were derived from isatin as a model, while assignments of glyoxylic derivatives were made by complete assignment of compound 8b together with its use as a model.
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